This page has been reformatted by knovel to provide easier navigation. Qualitative and quantitative analyses for ettringite, including xray diffraction xrd and differential thermal analysis dta. Delayed ettringite formation request pdf researchgate. Principal specialist, engineering practice tetra tech eba inc. The art of exploitation written by jon erickson is very useful for computer science and engineering cse students and also who are all. Moreover ettringite formation cam be advantageously used without any sulfate attack on concrete. Ettringite and monosulfate are also thought to occur in minute crystals closely intermixed with and occupying space within individual inner product or hydrated phenograin csh deposits in ordinary. Introduction changes in the cement manufacturing process such as the use of higher sulfur fuels, reduced dust wasting and lower. Abstract ettringite is commonly formed at early ages in concrete cured under ambient conditions. The term delayed ettringite formation def was first used in the literature in the 1980s to explain the deterioration of steamcured precast concrete structures, due to the development of a significant amount of secondary ettringite in cracks and matrixaggregate interfaces, in spite of being sulfate ion free. Ettringite formation and sulfate attack on concrete synopsis. To induceopening and the softening function itself are all delayed ettringite formation the studied concretes were.
The two main chemicals attacks to concrete are attributed to alkaliaggregate reaction aar and the action of sulphates, among which stands out the delayed ettringite formation def delayed ettringite formation. Different exposure conditions were investigated while other parameters such as watertocement. Deterioration processes and standard test methods, 2010. Delayed ettringite formation rocesses and problems 209 fig. Lessons learned from structures damaged by delayed. Pdf delayed ettringite formation fami fami academia. Delayed ettringite formation has been a significant problem in many countries. One of the first publications about concretedamaging late ettringite formation appeared. Delayed ettringite formation def failure mechanisms. Damage due to the delayed ettringite formation allegedly occurs when material is exposed to temperatures higher than 70c 3,4. Normally, at early ages, ettringite all transfers to afm phase. The effect of delayed ettringite formation on fine grained.
It can take up to 20 years for cracking to become apparent. Delayed ettringite formation def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite which is a normal product of early cement hydration. In the worst cases it has caused loss of serviceability of the affected concrete structure. In this paper, the effect of fly ash on delayed ettringite formation of heatcured cementbased mortars was investigated.
Introduction the problem of durability of concrete with cement as binding material comes more and more to the fore with the increased use of concrete, with the changed production and utilization. Preventing alkalisilica reaction and delayed ettringite. It has been proposed that def expansion is affected by. The objective of the study included investigating the possible presence of def in castinplace concrete. Procedures for quantifying the potential degree of future def development in concrete, using accelerated hydration and dta determination of any additional ettringite developed. The art of exploitation written by jon erickson is very useful for computer science and engineering cse students and also who are all having an interest to develop their knowledge in the field of computer science as well as information technology. Effects of calcium sulfate and aluminum crystal forms on.
The mechanism of expansion is still the subject of research. Delayed ettringite formation def is an internal sulfate attack caused by. Delayed ettringite formation delayed ettringite formation is a less common, but potentially more damaging, cause of distress than asr. The objective of the research included investigating possible presence of def, correlations between the presence of def in castinplace concrete and moist map cracking, and correlations between presence of def in castinplace concrete and air entrainment agents aea. The latter is caused by the delayed formation of ettringite in a cementitious material and occurs in particular because of a significant heating of the concrete. Alkalisilica reaction asr and delayed ettringite formation def, or combinations of the two, have been found to be the main causes of these problems. Delayed ettnngite formation def is an endogenous reaction which can cause deterioration in concrete. Chemical and petrographic analyses and astm test procedures. Pdf charactherization of delayed ettringite formation in.
The term premature concrete deterioration pcd has been adopted to refer to problems associated with asr and def because it is often difficult to distinguish between them. The modernized delayed benoni modernized reti benoni benoni defense modern benoni the modernized reti, a complete repertoire. Damaged concretes often show large amounts of ettringite in structure damages even if they we. It is a normal product in concrete and is delayed when the temperature rises too high for it to form. There have been far fewer documented cases of def than of asr, and prior to this project, there were no published cases in which def was the sole culprit in causing deterioration in an actual field structure. The modernized delayed benoni modernized reti benoni benoni defense modern benoni the modernized reti, a complete repertoire for white 771. Ettringite is a normal product in concrete and is delayed when the temperature rises too high. The objective of the research included investigating possible presence of. There have been far fewer documented cases of def than of. Delayed ettringite formation def is known as the deterioration phenomenon that occurs in mortar or concrete cured at high temperature.
Significance of delayed ettringite formation and damage. In turn, the durability of concrete structures can often be affected by chemical attacks, endangering its performance and safety. Water is a critical element in the formation of ettringite. Compressive strength and young modulus decrease when definduced expansion exceeds 0. Delayed ettringite formation def is a relatively rare but potentially severe form of internal sulphate attack of concrete. Delayed ettringite formation def is a chemical reaction that causes expansion in civil engineering structures. Delayed ettringite formation def in precast concrete. Delayed ettringite formation def is a possible autogenous expansive reaction of concrete. The combination of mellowing time and moisture content that achieves this goal is selected. Relationship between delayed ettringite formation and delayed expansion in massive. Structures of the 2016 annual conference of the transportation association of canada toronto, on abstract. British standards 2971 code british standards 2971 delayed ettringite formation british standards bs 2971 pdf english language standards social. In the worst cases it has caused loss of serviceability of the.
Recommendations for preventing disorders due to delayed ettringite. The objectives of this research were to experimentally study the influence of exposure conditions on delayed ettringite formation def in mortar specimens, and to explore the complex processes of expansive cracking associated with def. Please click on the previous link to view the papers available, or call 248. The expansive sulphate internal reaction due to delayed ettringite formation def can damage concrete structures severely. Effect of high curing temperatures on the strength. Controlling ettringite formation recommended practice for. The safety level of such damaged structures has to be reassessed. The term premature concrete deterioration pcd has been adopted to refer to problems associated with asr and def because it is often difficult to distinguish between. Request pdf delayed ettringite formation delayed ettringite formation def can. Delayed ettringite formation def can damage concrete that has experienced a temperature above about 70c. The effect of the partial cement substitution with fly ash on. Smaller but distinct ettringite deposits on oppo site sides of a sand grain. Fracture properties of concrete exposure to delayed.
Test methods were designed to trigger reaction in concrete specimens and determine how ambient rh affects expansion of the specimens. Delayed ettringite formation def is a pathology that induces concrete. Although many papers have been written on case studies of incidences of delayed ettringite formation def, few demonstrate a careful study of the methods of analyses for the presence and concentration. Delayed ettringite formation def in precast concrete fear, facts and risks bozena czarnecki, ph. Delayed ettringite formation def in cementitious materials is considered as a harmful chemical reaction leading to a variety of damages. Using typical fdot class iv mass concrete mixes it was found that elevated curing temperatures resulted in lower laterage strengths. Lessons learned from structures damaged by delayed ettringite.
The primary ettringite a hydrous calcium trisulphoaluminate is a normal reaction. The formation of ettringite or cement bacillus has been recognized as the cause of excessive expansion, cracking and even complete disintegration of concrete subjected to intensive sulfate attack. Saturated salts solutions were used to achieve distinct ambient rh conditions within. Delayed ettringite formation in concrete structures. Delayed ettringite formation is still an open question.
Secondary ettringite formation in concrete subjected to. The objectives of this research were to experimentally study the influence of exposure conditions on delayed ettringite formation def in mortar specimens, and to explore the complex processes of. Civil engineering faculty, leonardo da vinci, politechnic. The results favour the view that the expansion that can be associated with delayed ettringite formation is driven by processes occurring within the paste and not by the formation of ettringite at aggregate interfaces. Ettringite formation and sulfate attack on concrete by m. Concrete, sulphate attack, ettringite, delayed ettringite formation. Significance of delayed ettringite formation and damage mechanisms the primary ettringite formation in the initial stage of the hydration is seen as a positive effect because it read more. Accelerated test for measuring sulfate resistance of. This information paper, which is mainly concerned with insitu concrete, identifies circumstances in which def may cause problems. Ettringite is also known as c ement bacillus, which is the name of a naturally occurring mineral of the same composition and structure. The volume of the formed def crystals in the hardened concrete is larger than the volume of reactants, which results in forces from the growing crystals acting upon the walls of the crack. Delayed ettringite formation processes and problems.
During this period of high temperatures above 158f176f, the sulfate in cement paste starts to concentrate for a longer than usual period of time. The effect of natural pozzolan on delayed ettringite formation of the. Risk analysis of the delayed ettringite formation in pile caps foundation in the metropolitan region of recife pe brasil article pdf available june 2016 with 144 reads how we measure reads. Ettringite formation and the performance of concrete portland. Risk analysis of the delayed ettringite formation in pile. Alkalisilica reaction and delayed ettringite formation. Claims that slow release of sulfate from the clinker can have a similar effect in concrete not thus heated are unsupported. Aci committee 201, guide to durable concrete, aci manual of concrete. Def is a result of high early temperatures above 70 o c 80 o c in the concrete which prevents the normal formation of ettringite. Precastprestressed concrete institute, manual for quality control. It can affect materials that have experienced temperatures higher than about 65 c at early age. It occurs in concrete which has been cured at elevated temperatures, for example, where steam curing has been used. The research investigated the significance of delayed ettringite formation def presences in the maryland bridge inventory.
The observations made in studying these model systems are used as the. The purpose of extending mellowing time before compaction in soils is to force ettringite formation prior to compaction of pavement layers. The two main chemicals attacks to concrete are attributed to alkali. Influence of relative humidity on delayed ettringite formation. These tests are part of an ongoing series of experiments designed to help. To induceopening and the softening function itself are all delayed ettringite formation the studied concretes were elaborated using cements with appropriate sulfate contents, exposed to elevated temperature at an early age and then stored under water for 180. After several months or years, ettringite can form again if a new source of sulfate becomes available in the pore solution of the paste, viz. The formation of ettringite causes the concrete to expand, and empty cracks gaps may form around aggregates see figure 2.
Pdf risk analysis of the delayed ettringite formation in. Thus, the elimination of ettringite formation by hightemperature curing requires the presence of hydrating c 3 s. Delayed ettringite formation def is seen as a form of internal sulfate attack of cementitious materials, caused by early age heating to a temperature higher than 70c. This experimental study aims to determine the effect of relative humidity on concrete expansion due to delayed ettringite formation def, which still remains imperfectly known. The primary ettringite formation in the initial stage of the hydration is seen as a positive effect because it enables the setting regulation, a damaging role is often attributed to delayed ettringite formation in hardened concrete. Delayed ettringite formation how is delayed ettringite. The stability of ettringite advances in cement research.
In addition, the solvent exchange used to remove free water resulted in. Its gradual formation in the cooled, set concrete can lead to expansion and cracking in a process known as delayed ettringite formation def. Delayed ettringite formation is a consequence of improper heating during the curing process. Reproduction of delayed ettringite formation def in. Larbi, in nondestructive evaluation of reinforced concrete structures. Delayed ettringite formation is a relatively rare and controversial phenomenon in concrete deterioration, strongly related to the practice of heat curing. This information paper, which is mainly concerned with insitu concrete, identifies the circumstances in which delayed ettringite formation may cause problems. There were no indications that this latter process disrupted the surrounding material. Pdf ettringite formation and the performance of concrete. Volume stability of concrete relative to delayed ettringite formation def and optimum so3 content in portland cement. Delayed ettringite formation def is a special case of internal sulfate attack. Delayed ettringite formation def may be defined as the formation of ettringite in a cementitious material by a process that begins after hardening is substantially complete and in which none of the sulfate comes from outside the cement paste. Delayed ettringite formation def in precast concrete fear. Internal sulphate attack isa occurs in a sulphatefree environment when the.
Delayed ettringite formation in concrete imx technologies. Delayed ettringite formation in concrete jochen stark, katrin bollmann bauhausuniversity weimar germany 1. Delayed ettringite formation archives civildigital. The formation of ettringite or cement bacillus has been recognized. Many in the industry consider ettringite a negative ingredient because delayed ettringite formation, frequently a result of high concrete temperatures or exposure to sulfates, causes deterioration. These tests are part of an ongoing series of experiments designed to help understand the factors controlling the formation of ettringite in calciumrich cubs. Collepardi civil engineering faculty, leonardo da vinci, politechnic milan, italy abstract. To fulfil the aim of this study, a portion of cement was replaced by class ffly ash, with three. Maryland is a state in the eastern part of the united states. The study investigated the possible presence of delayed ettringite formation def in the maryland bridge inventory. At the present time, there is no selective and predictive test for def this paper describes the results of a study aimed at developing a test based on drying and wetting cycles.
Delayed ettringite formation, 46 september 2002, villars, switzerland 29 1. On the other hand, isa occurs in a sulfatefree environment due to the interaction of. Effects of calcium sulfate and aluminum crystal forms on the. Two nondestructive test ndt methods, potassium autoradiography and impactecho, were utilized in the study.
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